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Science · Atoms and particles

Atomic counts: identity, mass number and charge

Several numbers can describe the same atom, yet they answer different questions. Atomic number identifies an element by its proton count. Mass number counts protons and neutrons together. Electrical neutrality concerns the balance of positive and negative charge. Before calculating, write which of these questions the prompt actually asks.

The examples keep the particle counts explicit. You do not need a table of every element or a model of the electron’s path to solve them. Use a simple list headed protons, neutrons and electrons, then mark the entries needed for the requested number or comparison.

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Use the proton count for the element’s identity

Atomic number is the number of protons. Changing that count changes the element being identified. The number of neutrons or electrons is not a substitute for the proton count when the question asks for atomic number. Keep the definition beside your particle list.

Mass number combines the proton and neutron counts. In the stated example, six protons and eight neutrons give 6 + 8 = 14. This is a particle count named mass number, rather than a measurement of an atom’s mass in grams.

Neutrality compares opposite charges

A proton has a positive charge and an electron a negative charge of equal magnitude. Equal counts balance in an electrically neutral atom. The question asks you to compare those two counts, rather than add every particle in the list.

Use the same list to review all three examples. Circle only protons for atomic number, protons plus neutrons for mass number, and the proton/electron comparison for neutrality. Explain why the unmarked entry is not used in each case. This checks the selection of information before the arithmetic and prevents one familiar number from becoming an answer to every atomic question.

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Example 1 · Chemistry: atoms and the periodic table

The atomic number that identifies an element counts what?

  1. Neutrons
  2. Protons plus neutrons
  3. Only outer-shell electrons
  4. Protons
Read the answer and explanation

Answer: Protons

Changing the proton number changes the element.

Sources for this example

  • OpenStax Chemistry 2e — Ch. 2 Summary

    Basic facts and equations in this chapter concerning matter, atoms, reactions, or equilibrium. The questions, choices, and explanations were independently authored.

    Source checked: 2026-10-03

Example 2 · Chemistry: atoms and the periodic table

An atom has 6 protons and 8 neutrons. What is its mass number?

  1. 2
  2. 14
  3. 6
  4. 8
Read the answer and explanation

Answer: 14

Mass number is the sum of protons and neutrons: 6 + 8 = 14.

Sources for this example

  • OpenStax Chemistry 2e — Ch. 2 Summary

    Basic facts and equations in this chapter concerning matter, atoms, reactions, or equilibrium. The questions, choices, and explanations were independently authored.

    Source checked: 2026-10-03

Example 3 · Chemistry: atoms and the periodic table

How do the numbers of protons and electrons compare in an electrically neutral atom?

  1. There are always more electrons
  2. There are always more protons
  3. Both numbers are always zero
  4. They are equal
Read the answer and explanation

Answer: They are equal

Equal amounts of positive and negative charge balance.

Sources for this example

  • OpenStax Chemistry 2e — Ch. 2 Summary

    Basic facts and equations in this chapter concerning matter, atoms, reactions, or equilibrium. The questions, choices, and explanations were independently authored.

    Source checked: 2026-10-03

Sources for this guide

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